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Oxidative cleavage of ketoximes to ketones using photoexcited nitroarenes

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By Stefan Wiesler, Richmond Sarpong, Latimer Hall
| Royal Society of Chemistry Verified
Oxidative cleavage of ketoximes to ketones using photoexcited nitroarenes† The methoxime group has emerged as a versatile directing group for a variety of C–H functionalizations. Despite its importance as a powerful functional handle, conversion of methoximes to the parent ketone, which is often desired, usually requires harsh and functional group intolerant reaction conditions.
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