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Circular Heterochiral Titanium-Based Self-Assembled Architectures
CCDC 2253092–2253097 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/data_request/cif, or by emailing data_request@ccdc.cam.ac.uk, or by contacting The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336033. Terms & Conditions Most electronic Supporting Information files are available without a subscription to ACS Web Editions.
From monomeric complexes to double-stranded helicates constructed around trans-TiO4N2 motifs with intramolecular inter-ligand hydrogen-bonding interactions
A coordination chemistry involving trans-TiO N motifs is described, where the oxygen ligands are 2,2′-biphenolato derivatives (L or L ) and the nitrogen ligands are pyridine (Pyr), 2,3-dihydro-7-azaindole (DHA) or 2-(methylamino)pyridine (MePyr). Monomeric complexes and double-stranded helicates incorporating this set of ligands are characterized.
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