Leonard J. Barbour
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Methane storage using metal–dipyrazolate frameworks
Abstract Adsorbed natural gas storage using porous materials at ambient temperature and relatively low pressure promises to address safety and cost concerns of conventional natural gas storage technologies (liquefaction and compression), but its utility is hindered by low deliverable capacity. Flexible porous materials such as metal–organic frameworks can exhibit isotherms with the potential to afford enhanced deliverable capacity.
Healing crystals without heat - Nature Materials
An organic crystal repairs itself, even in liquid nitrogen, by using a dipole-driven mechanism rather than relying on thermal diffusion.
The Chemistry of Space: From Crystallographic Abstraction to Framework Design
The 2025 Nobel Prize in Chemistry, awarded “for the development of metal–organic frameworks”, celebrates not only a class of materials but also the power of abstraction born from crystallography itself — an idea that began when simple educational models were reimagined as blueprints for extended frameworks.
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