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Lianbang Wang

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Solvent polarizability governs Li⁺ transport kinetics for high energy lithium metal batteries

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By Chuangchao Sun, Linxiang Chen, Junyi Hua, Shengpeng Zhang, Yong Li, Liyi Zhao, Daixin Ye, Haikuo Zhang, Xiulin Fan, Lianbang Wang
| Nature Verified
Abstract Fast Li+ kinetics are essential for high energy lithium metal batteries, yet the factors governing these kinetics remain unclear. Here, we decipher a quantitative structure-kinetics relationship by demonstrating that polarizability dictates Li+ desolvation and transport. Specifically, the inert solvents with low polarizability generate weak induced dipoles under interfacial electric fields, which keeps the structural integrity of anion-rich solvates.
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