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Anomeric memory of the glycosidic bond upon fragmentation and its consequences for carbohydrate sequencing
In traditional IR spectroscopy, the 3?µm spectral range is of little molecular specificity due to the interferences with aqueous solvents. For carbohydrates in the gas phase however, this spectral range is highly specific, as established by the pioneering work of Simons25 on jet-cooled, synthetically phenyl-grafted monosaccharides and oligosaccharides26, 27.
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