Loris Lombardo
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1D axial heterostructure of hydrogen-bonded framework and metal-organic framework by metalation reaction - Nature Communications
Abstract Creating one-dimensional (1D) axial heterostructures of crystals formed from hydrogen-bonded organic frameworks (HOFs) and metal-organic frameworks (MOFs) is challenging due to their distinct chemical bonds to construct each porous architecture. In this study, we applied the metalation process, exchanging H+ with monovalent metal cations, to fabricate bulk crystal 1D axial heterostructures of HOF and MOF.
Solvent- and Catalyst-free Reduction of CO2 with Ammonia Borane
Solvent- and Catalyst-free Reduction of CO2 with Ammonia Borane Ammonia borane (AB) has been extensively studied as a solid-state hydrogen storage material. On the other hand, its reactivity with CO2 is still unclear, especially in the solid state. By carefully controlling the CO2 pressure and temperature, AB efficiently reduces a large amount of CO2 without solvent or catalyst. 40 mmol of CO2 reacts with one mole of AB at 0.5 MPa and 60 ℃. The mechanism was investigated by NMR and DFT calculation.
Synthesizing Interpenetrated Triazine‐based Covalent Organic Frameworks from CO2
Conflict of interest The authors declare no conflict of interest. Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.
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