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Thermoresponsive Behavior of Poly(acrylic acid-co-acrylonitrile) with a UCST

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By X. X. Zhu, Chuanzhuang Zhao, Louis Dolmans
| American Chemical Society
Poly(acrylic acid) is water soluble but can be converted into a thermoresponsive polymer possessing an upper critical solution temperature (UCST) by copolymerizing with acrylonitrile. The copolymers showed a UCST in water under ambient conditions, driven by the combined effect of hydrogen bonding between the carboxylic acid groups and hydrophobic interaction among the acrylonitrile moieties.
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