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Molecular Engineering of 3-Arylated Tetrazo[1,2-b]indazoles: Divergent Synthesis and Structure-property Relationships
Molecular Engineering of 3-Arylated Tetrazo[1,2-b]indazoles: Divergent Synthesis and Structure-property Relationships The synthetic scope of 3-arylated tetrazo[1,2-b]indazoles is reported based on a Liebeskind-Srogl cross-coupling reaction followed by a N-cyclisation process. The reactivity of the nitrogen atoms was used to further diversify these N-rich polyaromatics tetrazo[1,2-b]indazoles in a panel of reactions (protonation, selective oxidation, metallations).
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