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Stereospecific Access to α-Haloalkyl Esters via Enol Ester Epoxides and Synthesis of a C3–C21 Fragment of Bastimolide A We report a 14-step synthesis of a C3–C21 fragment of bastimolides A and B, antimalarial macrocyclic polyketides. A crucial ring-opening reaction of an enol ester epoxide showed previously unexplored reactivity, leading to an asymmetric synthesis of α-haloalkyl esters.
Businesses are increasingly addressing WASH in the workplace, often within the broader context of mainstreaming water stewardship, improving worker welfare and the realization of the human rights to water and sanitaion. However, to meet the ambition of the SDGs more needs to be done, especially to reach women and girls.
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