Luckym V. Dinh on Muck Rack

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Comparing Interactions of a Three-Coordinate Pd Cation with Common Weakly Coordinating Anions

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By William A. Sabbers, Kushan C. Weerasiri, Luckym V. Dinh, Jacqueline L. Quenzer
| American Chemical Society
A series of complexes Pd(IPr)(C(O)C H N)X has been prepared where X is a weakly coordinating anion (WCA). [Pd(IPr)(C(O)C H N)]+ can be isolated as a 3-coordinate, air- and moisture-stable Pd(II) cation when paired with sterically encumbered WCAs. Using NMR, IR, X-ray diffraction, and computational (DFT, NBO) techniques, the coordination ability of WCAs in both solid and solution state is compared.
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