Maniklal Shee

Abstract Click to copy section linkSection link copied! Precise control of excited-state electronic communication and spin dynamics is critical for advancing optoelectronic properties and the photocatalytic function of purely organic materials.

Interrogating bioinspired ESIPT/PCET-based Ir(iii)-complexes as organelle-targeted phototherapeutics: a redox-catalysis under hypoxia to evoke synergistic ferroptosis/apoptosis† Installing proton-coupled electron transfer (PCET) in Ir-complexes is indeed a newly explored phenomenon, offering high quantum efficiency and tunable photophysics; however, the prospects for its application in various fields, including interrogating biological systems, are quite open and exciting.

Chemical versatility of azide radical: journey from a transient species to synthetic accessibility in organic transformations Maniklal Shee a and N. D. Pradeep Singh *a Abstract The generation of azide radical (N3˙) occurs from its precursors primarily via a single electron transfer (SET) process or homolytic cleavage by chemical methods or advanced photoredox/electrochemical methods. This in situ generated transient open-shell species has unique characteristic features that set its reactivity.