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Mantra Dheendayal

As seen in: ACS Publications
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Articles

Enhanced Electron Transfer Rates Between Surface-Attached Dye Molecules with Large Pendant Moieties and Co3+/2+ Complex Redox Mediators

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By Mantra Dheendayal, Pawel Wagner, Shogo Mori, Attila J. Mozer
| dx.doi.org
Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Phys. Chem. C 2024, XXXX, XXX Terms & Conditions Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses).
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High Electronic Coupling between Cu Complexes and Oxidized Dyes Confirmed by Measurements of Driving Force Dependent Regeneration Kinetics in Minimal Electrolyte System

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By Mitsuru Narita, Mantra Dheendayal, Pawel Wagner, Shogo Mori
| dx.doi.org
We confirm fast regeneration kinetics between copper complexes and oxidized organic dyes and the major contribution of electronic coupling (HDA). The highest efficiency of dye-sensitized TiO2 solar cells has been shown by employing Cu complex redox couples. Various groups have reported a fast regeneration rate of oxidized dyes by Cu complexes giving a low driving force attributed to low reorganization energy (λ), but the effect of HDA has not been evaluated.
Open in Who Shared Issue with article?

High Electronic Coupling between Cu Complexes and Oxidized Dyes Confirmed by Measurements of Driving Force Dependent Regeneration Kinetics in Minimal Electrolyte System

|
By Mitsuru Narita, Pawel Wagner, Shogo Mori, Mantra Dheendayal
| ACS Publications
We confirm fast regeneration kinetics between copper complexes and oxidized organic dyes and the major contribution of electronic coupling (HDA). The highest efficiency of dye-sensitized TiO2 solar cells has been shown by employing Cu complex redox couples. Various groups have reported a fast regeneration rate of oxidized dyes by Cu complexes giving a low driving force attributed to low reorganization energy (λ), but the effect of HDA has not been evaluated.
Open in Who Shared Issue with article?
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