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Manuel Barday

As seen in: Color Research & Application, Wiley Online Library
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Articles

Photoinduced Cobalt Catalysis for the Reductive Coupling of Pyridines and Dienes Enabled by Paired Single‐Electron Transfer

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By Manuel Barday, Samikshan Jana, Nil Sanosa, Jingyang Qin
| pericles.pericles-prod.literatumonline.com
Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.
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Photoinduced Cobalt Catalysis for the Reductive Coupling of Pyridines and Dienes Enabled by Paired Single‐Electron Transfer**

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By Jingyang Qin, Manuel Barday, Samikshan Jana, Nil Sanosa
| Wiley Online Library Verified
Introduction Dienes are readily-available feedstocks which are ideal starting materials for fine-chemical synthesis.1 Their regioselective catalytic hydrofunctionalisation offers a potentially straight-forward, efficient route to a single product in a manner that cannot be matched by other approaches such as allylic hydrogen atom abstraction which face selectivity issues (Scheme 1a).2-5 The resulting products are versatile building blocks which contain a C=C bond in proximity to the newly...
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Cross-Coupling of α-Carbonyl Sulfoxonium Ylides with C−H Bonds

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By James Muir Verified, Christophe Aïssa, Manuel Barday, Christopher Janot, Nathan R. Halcovitch
| Color Research & Application Verified
The functionalization of carbon–hydrogen bonds in non-nucleophilic substrates using ?-carbonyl sulfoxonium ylides has not been so far investigated, despite the potential safety advantages that such reagents would provide over either diazo compounds or their in situ precursors. Described herein are the cross-coupling reactions of sulfoxonium ylides with C(sp2)?H bonds of arenes and heteroarenes in the presence of a rhodium catalyst.
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