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Articles by Marcel Baumert
Overcrowded Alkene Photo-Redox-Switches Based on Quinolinium/Carbene Building Blocks
1 Introduction Stimuli-driven reversible change of a molecular structure triggering motion on a molecular level is a highly vibrant area of research with plenty of applications. In particular light driven molecular switches, which can change between two or more states, have gained significant attention and achieved a multitude of different applications ranging from material science [1-3] over catalysis [4-6] and molecular machines [7-10] to biological applications [11, 12].
Nicht-Wissen als Wirkprinzip
Ethik Mut zum Nicht-Wissen im Coaching – die Philosophie Zhuangzis ermöglicht ein bewusstes Loslassen von starrem Wissen als Wirkprinzip. Der antike chinesische Philosoph betrachtete Wissen oft als Hindernis zur Erkenntnis. Diese Haltung schafft Raum für unerwartete Möglichkeiten und neue Lösungen, indem der Coach zum flexiblen Navigator im Unbekannten wird, der sich auf achtsame Orientierung und Vertrauen in den Prozess verlässt.
para‐Aminoazobenzenes-Bipolar Redox‐Active Molecules - Schatz - Angewandte Chemie International Edition - Wiley Online Library
Introduction Since their discovery in 1834 by Mitscherlich, azobenzenes (ABs) have continuously been present in chemical research.1 The straightforward synthesis of simple ABs, and their bright coloration sparked their application in the dye industry, where still today 70 % of the total dye production is based on these diazenes.2 The work of Domagk at the IG Farben (German for “Dye industry syndicate stock corporation”), where the antibacterial properties of diazene dyes were studied, was...
Dicationic Acridinium/Carbene Hybrids as Strongly Oxidizing Photocatalysts
Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Am. Chem. Soc. 2024, XXXX, XXX CCDC 2306482–2306488 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/data_request/cif, or by emailing data_request@ccdc.cam.ac.uk, or by contacting The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336033.
From Squaric Acid Amides (SQAs) to Quinoxaline-Based SQAs─Evolution of a Redox-Active Cathode Material for Organic Polymer Batteries
Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Am. Chem. Soc. 2023, XXXX, XXX CCDC 2289869–2289873 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/data_request/cif, or by emailing data_request@ccdc.cam.ac.uk, or by contacting The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336033.
Ruthenium(II) oxidase catalysis for C-H alkenylations in biomass-derived γ-valerolactone
Ruthenium(II) biscarboxylate oxidase catalysis is a powerful tool for the assembly of functionalized arenes with oxygen as a green oxidant, but this strategy was thus far limited to its use in traditional organic solvents. Herein, we report on a green procedure for the ruthenium(II) biscarboxylate-catalysed C–H functionalisation in biomass-derived ?-valerolactone as the reaction medium.
Ruthenium(ii) oxidase catalysis for C-H alkenylations in biomass-derived γ-valerolactone - Green Chemistry (RSC Publishing)
Ruthenium( ) biscarboxylate oxidase catalysis is a powerful tool for the assembly of functionalized arenes with oxygen as a green oxidant, but this strategy was thus far limited to its use in traditional organic solvents. Herein, we report on a green procedure for the ruthenium( ) biscarboxylate-catalysed C–H functionalisation in biomass-derived ?-valerolactone as the reaction medium.
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