Massimo Baroncini
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Wavelength-steered directional rotation in an autonomous light-driven molecular motor - Nature Chemistry
Abstract Artificial molecular motors are at the forefront of research in nanotechnology due to their ability to perform tasks by harnessing directionally controlled motion at the molecular scale. The development of light-driven nanomotors is a particularly challenging task that holds great potential for the development of sunlight-powered systems and active materials.
Directional Ring Translocation in a pH‐ and Redox‐Driven Tristable [2]Rotaxane
Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.
Directional Ring Translocation in a pH‐ and Redox‐Driven Tristable [2]Rotaxane
Introduction Rotaxanes are an extensively explored class of mechanically interlocked molecules (MIMs),1 with particular significance in the field of molecular machines and motors.2 The minimal system is represented by a [2]rotaxane, composed of an axle-like molecule surrounded by a macrocycle, which cannot dethread by virtue of the presence of bulky units at the extremities of the axle.3 The presence of complementary recognition sites on the axle and macrocyclic components is generally...
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