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Articles by Mukesh Kumar Nayak
Smart Energy Council
GoodWe and Amber have launched their new integration, enabling access to Amber’s SmartShift technology for compatible GoodWe ESA home energy storage systems. Australian households in ACT, NSW, SA, SE QLD and VIC with eligible GoodWe ESA battery systems now have a new way to put their stored energy to work. The integration between GoodWe and Amber is now publicly available. It follows extensive development, testing, and a staged beta program between the two companies.
Pacific pre-COP delivers practical solar partnership for regional energy security
Fiji, 8 October 2026 – A new Australia-Pacific solar mentoring program launched in Fiji today will turn climate cooperation into practical support for Pacific installers – advancing energy sovereignty and security across the region.
Victoria Lower Power Bills Expo
The Smart Energy Council is proud to be leading an exciting initiative to help Victorian homeowners, businesses & community facilities, better understand the benefits of solar, battery storage, and home electrification. At each event, homeowners, businesses & community members, will attend to learn practical, real-world ways to reduce their energy bills and transition to electric homes.
The Pacific COP: Australia’s Moment to Shine
On the eve of a busy month of climate diplomacy for Prime Minister Anthony Albanese – beginning with his attendance at the Pacific Islands Forum in Solomon Islands this week – the Smart Energy Council has released a major new report, The Pacific COP: Australia’s Moment to Shine. A Global, Regional and Domestic Context The report sets out the context for COP31, including the agenda Australia will inherit if its bid to host – in partnership with Pacific nations – is successful in the coming months.
Effect of N-Heterocyclic Carbene in Palladium-Tin Heterobimetallic Catalysis: A DFT Supported Study on the C3-H Functionalization of Unprotected Indole.
Effect of N-Heterocyclic Carbene in Palladium-Tin Heterobimetallic Catalysis: A DFT Supported Study on the C3-H Functionalization of Unprotected Indole. A new N-heterocyclic carbene (NHC) based Pd-Sn heterobimetallic complex [(NHC)Pd(μ-Br)SnCl3]2 with a low steric crowding in the active catalytic region was designed. The reactivity of this complex was compared with a previously reported NHC-Pd-Sn complex (NHC)2PdBrSnCl3 towards the C3-H functionalization of indoles with styrenes.
SnCl2 Catalyzed Multicomponent Coupling: Synthesis of 1,3-Oxazolidine Derivatives Using Paraformaldehyde as a C1 Feedstock
SnCl2 Catalyzed Multicomponent Coupling: Synthesis of 1,3-Oxazolidine Derivatives Using Paraformaldehyde as a C1 Feedstock SnCl2 catalyzed three-component coupling of aniline, epoxide, and paraformaldehyde resulted in the synthesis of 1,3-oxazolidine derivatives. The reaction is simple and does not require any additive, base, or oxidant, and proceeds under moderate temperature with good functional group tolerance.
Aminocarbonylation Reaction Using a Pd-Sn Heterobimetallic Catalyst: Three-Component Coupling for Direct Access of the Amide Functionality
A heterobimetallic “Pd–Sn” catalyst, namely, PdCl(PPh3)2SnCl3, efficiently catalyzes the aminocarbonylation reaction of aryl iodides with amines under the atmospheric pressure of CO in the absence of a base and additive. Primary, secondary, and alkyl amines all afforded the corresponding amides in good to excellent yields with high selectivity. A broad range of functional groups were tolerated.
Aminocarbonylation Reaction Using a Pd-Sn Heterobimetallic Catalyst: Three-Component Coupling for Direct Access of the Amide Functionality
Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Org. Chem.
Pd-Sn Heterobimetallic Catalyst for Carbonylative Suzuki, Sonogashira and Aminocarbonylation Reactions using Chloroform as CO Surrogate
Pd-Sn Heterobimetallic Catalyst for Carbonylative Suzuki, Sonogashira and Aminocarbonylation Reactions using Chloroform as CO Surrogate Anuradha Mohanty, Mukesh Kumar Nayak and Sujit Roy Abstract Herein, we report a heterobimetallic Pd-Sn catalyst for the carbonylative Suzuki coupling, aminocarbonylation reaction, and carbonylative Sonogashira coupling of aryl halides with boronic acid, amine, and aromatic alkyne leading to a three-component coupling reaction using insitu generated carbon...
NHC as a Ligand in Heterobimetallic Catalysis: An Insight into a Catalytic Friedel-Crafts-like Reaction
The calculation of local reactivity descriptors, namely, local electron density and the Fukui function index for nucleophilic attack at a center, established that in transition metal–tin heterobimetallic complexes, N-heterocyclic carbene (NHC) is a better ligand than its alkene and phosphine analogues for the coupling of C–H and C–OH bonds.
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