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Nandini Barman

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Synthesis, Structure, and Magnetic Properties of Diamagnetic Co(III) ion-based Heterometallic CoIII-LnIII (Ln = Dy, Tb, Ho, Er) Complexes

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By Joydeb Goura, Enrique Colacio, Subrata Mukhopadhyay, Nandini Barman
| Royal Society of Chemistry Verified
Synthesis, Structure, and Magnetic Properties of Diamagnetic Co(III) ion-based Heterometallic CoIII-LnIII (Ln = Dy, Tb, Ho, Er) Complexes The reaction of Schiff base ligand N,Nʹ-Bis(salicylidene)ethylenediamine (H2L) with [CoII2(μ-OH2)(O2CCMe3)4(HO2CCMe3)4] (CoII2-Piv) (Piv = pivalate) and Ln(NO3)3·xH2O [for 1, 3, 4 x = 5; for 2, x = 6) salts in the presence of triethylamine afforded [CoIIILnIII(L)(μ-Piv)2(ɳ1-Piv)2(ɳ1-OHMe)2] [where Ln = Dy, for 1; Tb, for 2; Ho, for 3; and Er, for 4] complexes.
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