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REMO Self-Assembly Pathways Figure 5 compares the 31 P NMR spectrum of the A 1-mer and the UV–vis absorption spectrum of the D 1-mer with corresponding spectra of the AOnD oligomers. The 31 P NMR signals in the oligomer spectra are broadened, and in some cases, splitting is apparent, which is due to population of different rotamers around the exocyclic nitrogen triazine bond that are in slow exchange on the chemical shift time scale.
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