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Balancing Electroactive Backbone and Oligo(Ethylene Oxy) Side‐Chain Content Improves Stability and Performance of Soluble PEDOT Copolymers in Organic Electrochemical Transistors
1 Introduction The advantages of interfacing π-conjugated polymers with living systems have been reflected in recent years by numerous exploratory electrochemical and bioelectrical applications, such as optical displays,[1-3] energy storage devices,[4-7] neuromorphic computing elements,[8-11] and bioelectronic interfaces.[12-14] The ability of conjugated polymers to support coupled ion and electron transport is particularly beneficial for developing these bio-electronic interfaces, as they...
Effect of a benzothiadiazole spacer on transport properties and N-doping of naphthalene-diimide-based copolymers
Effect of a benzothiadiazole spacer on transport properties and N-doping of naphthalene-diimide-based copolymers† We report the synthesis of two n-type semiconducting polymers containing a naphthalene diimide (NDI) monomer and thiophene spacers. The two polymers differ by the introduction of an additional 2,1,3-benzothiadiazole (BTD) moiety in the polymer backbone.
Electrochemical Doping in Ordered and Disordered Domains of Organic Mixed Ionic-Electronic Conductors (Adv. Mater. 35/2023)
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