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Thermoelectric and Magnetic Behavior of (Eu/Yb/Mg)2Si Zintl Phases Grown in Magnesium-Based Flux
Cite Jump to ExpandCollapse ArticleFebruary 7, 2026 Thermoelectric and Magnetic Behavior of (Eu/Yb/Mg)2Si Zintl Phases Grown in Magnesium-Based Flux Click to copy article linkArticle link copied! Olufemi S. Araoyinbo Olufemi S.
Flux growth of La3MC2 (M = Sb, Bi, Te), a new family of ternary carbides
Reactions of carbon with a heavy main group metal (M = Sb, Bi, or Te) in an excess of lanthanum/nickel eutectic flux lead to formation of a family of carbide compounds La3MC2 with a new structure type. The monoclinic structure features C24- anions octahedrally coordinated by six La3+ cations, and M anions surrounded by 8 La3+ cations. These compounds are not charge-balanced and lie on the border between intermetallic carbides and mixed anion salts.
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