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Universal Group 14 Free Radical Photoinitiators for Vinylidene Fluoride, Styrene, Methyl Methacrylate, Vinyl Acetate, and Butadiene

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By Joon-Sung Kim, Abhirup Dutta, Vignesh Vasu, Olumide I. Adebolu
| American Chemical Society
Group 14 (Mt = Sn, Ge, Pb) R3MtX, R4Mt, and R6Mt2 complexes (R = alkyl, aryl; X = H, halide, etc.) are introduced as novel, universal, visible and black light bulb (BLB)/UV photoinitiators for free radical photopolymerization of alkenes, including vinylidene fluoride (VDF), vinyl acetate, methyl methacrylate, styrene, and butadiene.
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