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[3+2] Annulation of 2-(phenacylethylidene)cyclobutanones with thioureas for the preparation of cyclobutane-fused imidazolidine-2-thiones and thiazolidine-2-imines The [3+2] annulation reaction between a thiourea, an ambident dinucleophile, and a 2-(phenacylethylidene)cyclobutanone, containing a novel pull-pull alkene system, could in principle proceed with several chemo- and regioselectivity profiles.
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