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Ruthenium(0)-Mediated Successive N–H and S–H/C–H Bond Activation in Selected Imine Ligands: Elucidation of the Activation Mechanism and Application in Borrowing Hydrogen Catalysis
Abstract Click to copy section linkSection link copied! The reported study demonstrates the remarkable ability of the ruthenium(0) center in [Ru(CO)3(PPh3)2] to bring about σ-bond activation in organic molecules.
Ancillary ligand induced variation in electronic spectral and catalytic properties of heteroleptic ONO-pincer complexes of ruthenium
Ancillary ligand induced variation in electronic spectral and catalytic properties of heteroleptic ONO-pincer complexes of ruthenium Abstract: In this paper we report our studies on a group of mixed-ligand complexes of ruthenium(II) bearing a ONO-coordinated dipicolinate (DPA) as the pincer ligand, and some selected ancillary ligands (viz. PPh3, CH3CN, 4-picoline (pic), 2,2ʹ-bipyridine (bpy), and 1,10-phenanthroline (phen)).
Dipicolinate‐Ruthenium‐NHC/trpy Complexes: Pincer Ligand Induced Hemilability of Dipicolinate and Enhancement of Cytotoxic Property
Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.
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