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Paven Kisten

As seen in: Royal Society of Chemistry
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Articles

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By Paven Kisten, Sandrine Vincendeau, Eric Manoury, Jason Martin Lynam
| Royal Society of Chemistry Verified
Understanding ketone hydrogenation catalysis with anionic iridium(III) complexes: The crucial role of counterion and solvation The catalytic asymmetric hydrogenation of ketones reflect an important way to prepare valuable chiral alcohols. Understanding how transition metals promote these reactions is key to the rational design of more active, selective and sustainable catalysts.
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IrI(η4-diene) precatalyst activation by strong bases: formation of an anionic IrIII tetrahydride

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By Paven Kisten, Université de Toulouse, France CNRS, Eric Manoury
| Royal Society of Chemistry Verified
IrI(η4-diene) precatalyst activation by strong bases: formation of an anionic IrIII tetrahydride† Paven Kisten, ab Eric Manoury,b Agustí Lledós, c Adrian C. Whitwood, a Jason M. Lynam, a John M. Slattery, a Simon B. Duckett *a and Rinaldo Poli *bd Abstract The reaction between [IrCl(COD)]2 and dppe in a 1 : 2 ratio was investigated in detail under three different conditions. [IrCl(COD)(dppe)], 1, is formed at room temperature in the absence of base.
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