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Uncatalyzed, on water oxygenative cleavage of inert C-N bond with concomitant 8, 7-aminoshift in 8-aminoquinoline derivatives

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By Chandrasekharam Malapaka, Vinayak Botla, Pilli Navyasree
| Royal Society of Chemistry Verified
Uncatalyzed, on water oxygenative cleavage of inert C-N bond with concomitant 8, 7-aminoshift in 8-aminoquinoline derivatives Oxygenative cleavage of inert CAr-NH2 bond with concomitant 1, 2 amine migration in 8-aminoquinoline derivatives is reported in water at room temperature. The reaction is highly atom- and step- economical as both C- and N-containing fragments of the C-N bond cleavage are incorporated into the target molecule and is affected without the need for N-oxide.
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