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Randall Tyler Mertens

As seen in: Royal Society of Chemistry
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Articles

Self-assembled ruthenium and osmium nanosystems display potent anticancer profile by interfering with metabolic activity

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By Mickaël Marloye, Haider Inam, Randall Tyler Mertens, Aude AI Ingels
| Royal Society of Chemistry Verified
Self-assembled ruthenium and osmium nanosystems display potent anticancer profile by interfering with metabolic activity Mickael Marloye, Haider HI Inam, Connor J. CJM Moore, Randall Tyler Mertens, Aude AI Ingels, Marilin MK Koch, Michal O. MON Nowicki, Veronique Mathieu, Justin R. JRP Pritchard, Samuel Awuah, Sean E.
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Direct intramolecular carbon(sp2)-nitrogen(sp2) reductive elimination from Gold(III)

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By Samuel G. Awuah, Jong Hyun Kim, Randall Tyler Mertens, Sean R. Parkin
| Royal Society of Chemistry Verified
Direct intramolecular carbon(sp2)-nitrogen(sp2) reductive elimination from Gold(III) Detailed reactivity underlying bidentate AuIII-Cl species, [(C^N)AuCl2], with a bisphosphine or carbon donor ligands result in reductive elimination. Combined experimental and computational investigations lead to the first evidence of a direct intramolecular C(sp2)–N(sp2) bond formation from a monomeric [(C^N)AuCl2] gold(III) complex.
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Revisiting the Reactivity of Tetrachloroauric acid with N,N-Bidentate Ligands: Structural and Spectroscopic Insights.

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By Samuel G. Awuah, Jong Hyun Kim, William Jennings, Randall Tyler Mertens
| Royal Society of Chemistry Verified
Revisiting the Reactivity of Tetrachloroauric acid with N,N-Bidentate Ligands: Structural and Spectroscopic Insights. Samuel Awuah, Randall Tyler Mertens, Jong Hyun Kim, William Jennings  and Sean R. Parkin Abstract The reactivity of tetrachloroauric acid (HAuCl4) with readily accessible bidentate N-donor ligands affords N,N-ligated Au(III) center complexes. These compounds are useful precursors to stable catalysts, anticancer agents, and building blocks for materials.
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