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Chameleonic Reactivity of Imidoyl Sulfoxonium Ylides: Access to Functionalized Pyrroles and Dihydro-pyridines
CCDC 2293503 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/data_request/cif, or by emailing data_request@ccdc.cam.ac.uk, or by contacting The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336033. Terms & Conditions Most electronic Supporting Information files are available without a subscription to ACS Web Editions.
Chemo-, Regio- and Stereoselective Synthesis of Monofluoroalkenes via a Tandem Fluorination-Desulfonation Sequence
Chemo-, Regio- and Stereoselective Synthesis of Monofluoroalkenes via a Tandem Fluorination-Desulfonation Sequence You have access to this article Please wait while we load your content... Something went wrong. Try again?
Base Promoted gem-Difluoroolefination of Alkyl Triflones
Base Promoted gem-Difluoroolefination of Alkyl Triflones A new synthesis of gem-difluoroalkenes from readily available alkyl triflones and difluorocarbene precursors such as TMSCF2Br has been reported. The reaction, regardless of electronic effect, gives gem-difluoroalkenes in good to excellent yields. The mechanism may involve tandem deprotonation of triflones, nucleophilic addition, and the elimination of SO2CF3. You have access to this article Please wait while we load your content...
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