Renyuan Pony Yu on Muck Rack

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Synthesis, Structure, and Hydrogenolysis of Pyridine Dicarbene Iron Dialkyl Complexes

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By Jonathan M. Darmon, Peter Viereck, Renyuan Pony Yu, Tyler P. Pabst
| American Chemical Society
Two methods for the synthesis of bis(imidazol-2-ylidene)pyridine iron dialkyl complexes, (CNC)Fe(CH2SiMe3)2, have been developed. The first route consists of addition of 2 equiv of LiCH2SiMe3 to the iron dihalide complex (CNC)FeBr2, while the second relies on addition of the free CNC ligand to the readily prepared (py)2Fe(CH2SiMe3)2 (py = pyridine).
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