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Anomalous photochromism and mechanochromism of a linear naphthopyran enabled by a polarizing dialkylamine substituent
Anomalous photochromism and mechanochromism of a linear naphthopyran enabled by a polarizing dialkylamine substituent† In contrast to common angular naphthopyrans that exhibit strong photochromic and mechanochromic behavior, constitutionally isomeric linear naphthopyrans are typically not photochromic, due to the putative instability of the completely dearomatized merocyanine product.
Naphthopyran molecular switches and their emergent mechanochemical reactivity
Naphthopyran molecular switches and their emergent mechanochemical reactivity Naphthopyran molecular switches undergo a ring-opening reaction upon external stimulation to generate intensely colored merocyanine dyes. Their unique modularity and synthetic accessibility afford exceptional control over their properties and stimuli-responsive behavior.
A modular approach to mechanically gated photoswitching with color-tunable molecular force probes
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