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S. Bart Jones

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A maximally preorganized tetra‐pyridyl ligand. Rigid five‐membered chelate rings enhance selectivity for large metal ions, such as Th(IV), UO22+ and Lanthanides. A DFT and Thermodynamic study

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By Randolph P. Thummel, Hee-Seung Lee, Stuart Uritis, S. Bart Jones
| Wiley Online Library Verified
Introduction Oligopyridyl ligands are of interest in ligand design1, 2 in potential applications ranging from separating Am(III) from Ln(III) (Ln=lanthanide) ions in treating nuclear waste3-8 to the development of fluorescent sensors for metal ions.1, 9-18 Some recent reviews of interest in the field of oligopyridyl ligands are those of Constable19 and Bencini and Lippolis.20 Ligands based on PHEN (see Figure 1 for key to ligand abbreviations) with additional donor groups at the 2 and 9...
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