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Catalytic asymmetric approach to floral odorant, (+)- and (−)-Florhydral Author links open overlay panelDebabrata Mondal a , Dhruvilkumar Sureshkumar Patel b , Vishnumaya Bisai b Show more Highlights • Catalytic asymmetric approach to (+)-florhydral® (1a) and (−)-florhydral® (ent-1a). • Rh-(S)-BINAP (2 mol%) catalyzed 3-isopropylboronic acid conjugate addition (up to 90 % ee). • 2-Step synthetic approach to (+)- and (−)-florhydral® from commercially available precursors.
Asymmetric approach to aromatic bisabolanes via allylic diazene rearrangement (ADR): Total syntheses of (−)-curcumene, (−)-dihydrocurcumene, (−)-nuciferol, and (−)-nuciferal Author links open overlay panelDebabrata Mondal a , Spoorti B. Patil b , Achal Yeola b , Vishnumaya Bisai b Show more Highlights • Catalytic asymmetric approach to (−)-curcumene, (−)-dihydrocurcumene, (−)-nuciferol, and (−)-nuciferal.
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