Safwan Aroua on Muck Rack

Safwan Aroua

As seen in: ACS Publications, Royal Society of Chemistry
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Articles

Regioselective Synthesis and Characterization of Tris- and Tetra-Prato Adducts of M3N@C80 (M = Y, Gd)

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By Olesya Semivrazhskaya, Safwan Aroua, Maxim Yulikov, Adrian Romero-Rivera
| ACS Publications
The tris- and tetra-adducts of M3[email protected]Ih-C80 metallofullerenes were synthesized and characterized for the first time. The 1,3-dipolar cycloaddition (Prato reaction) of Y3[email protected]Ih-C80 and Gd3[email protected]Ih-C80 with an excess of N-ethylglycine and formaldehyde provided tris- and tetra-fulleropyrrolidine adducts in a regioselective manner.
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Structures of Gd3N@C80 Prato Bis-Adducts: Crystal Structure, Thermal Isomerization, and Computational Study

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By Adrian Romero-Rivera, Safwan Aroua, Sergey Troyanov, Olesya Semivrazhskaya
| American Chemical Society
The structures of two bis-ethylpyrrolidinoadducts of Gd3[email protected]Ih-C80, obtained by regioselective 1,3-dipolar cycloadditions, were elucidated by single crystal X-ray, visible-near infrared (vis-NIR) spectra, studies on their thermal isomerization, and theoretical calculations. The structure of the minor-bis-adduct reveals a C2-symmetric carbon cage with [6,6][6,6]-addition sites and with an endohedral Gd3N cluster that is completely flattened.
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Effect of Temperature and Solvent on the Structure of Amide Cavitands

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By Safwan Aroua, Marc‐Olivier Ebert, Yoko Yamakoshi, Ankita Ray
| Wiley Online Library Verified
Full Paper Effect of Temperature and Solvent on the Structure of Amide Cavitands Yoko Yamakoshi Corresponding Author E-mail address: yamakoshi@org.chem.ethz.ch Laboratorium für Organische Chemie, ETH Zürich, Vladimir-Prelog-Weg 3, CH-8093 Zürich, Switzerland Search for more papers by this author Dedicated to Prof. Dr. François Diederich PDF PDF Share Abstract Conformational changes of amide cavitands A–C were investigated at varied temperatures and in several solvents.
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