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Sarnali Sanfui

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Articles

Structural and Electronic Complexities of a Sulfur‐Bridged Di‐Iron Complex Composed of Mono‐ and Di‐Nitrosyl Units

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By Manuel Quiroz, Jialu Li, Feipeng Yang, Sarnali Sanfui
| Wiley Online Library Verified
1 Introduction Diatomic ligands such as CO, CN−, and NO+/0/− are central to the development of molecular structure and bonding principles related to atomic properties of the metals to which they are bound.[1-3] Carbon monoxide and cyanide are important natural components in primordial enzyme active sites, e.g. the hydrogenases.[4, 5] Prominent in biochemistry as well as human physiology, nitric oxide and its ability to traverse three redox states (NO+, NO, and NO−) are acknowledged as an...
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