Sergio Barranco

Abstract Directed hydrogen isotope exchange strategies have become an essential tool for accessing isotopically labelled organic scaffolds and interrogating the mechanisms of transition metal-catalysed C–H activation. However, the rationale behind deuterium source selection remains largely absent from the literature; an oversight that directly affects mechanistic interrogation strategies and hinders the development of new deuteration methodologies.

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Communication Monica Helvia Perez-Temprano Corresponding Author E-mail address: mperez@iciq.es Institute of Chemical Research of Catalonia, Barcelona Institute of Science and Technology, ICIQ, Avda. Paisos Catalans 16, 43007 Tarragona, SPAIN Search for more papers by this author PDF PDF Share Abstract Herein, we disclose the synthesis of metallacyclic Cp*Co III complexes containing weakly‐chelating functional groups.