Sidharam P. Pujari on Muck Rack

Sidharam P. Pujari

As seen in: Nature, Wiley Online Library, MDPI, ACS Publications
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Articles

Multimodal S(VI) Exchange Click Reactions Derived from SF2 Moieties: Comparative Kinetics and Stereochemistry of SuFEx and SuPhenEx Reactions

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By Yumei Zhu, Akash Krishna, Xixi Li, Sidharam P. Pujari
| ACS Publications
Introduction Click to copy section linkSection link copied! Click chemistry has significantly transformed materials science by providing an effective approach to structures with a wide range of molecular diversity.
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Synthesis of chiral sequence-defined oligomers via sulfur–fluoride and sulfur–phenolate exchange reactions - Nature Synthesis

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By Yu Han, Sidharam P. Pujari, Muthusamy Subramaniam, Fedor M. Miloserdov
| Nature Verified
Abstract Sequence-defined oligomers have been synthesized with increasing complexity, but the participation of chiral centres in the oligomerization process remains challenging. Here we report the synthesis of sequence-defined oligosulfonimidates (up to thirteen-mers) obtained via a series of sulfur–fluoride exchange and sulfur–phenolate exchange reactions.
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Configurationally Chiral SuFEx‐Based Polymers

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By Dong-Dong Liang, Sidharam P. Pujari, Muthusamy Subramaniam, Maarten Besten
| Wiley Online Library Verified
Abstract An intrinsically chiral SuFEx (sulfur–fluorine exchange) click reaction was used to produce a series of configurationally chiral high-molecular-weight polymers. This step-growth polymerization occurs with high efficiency and enantiospecifically (ee>98 %). Abstract Novel methods to make synthetic chiral polymers are highly desirable given their potential in a rapidly increasing number of bio-inspired applications.
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