Single-molecule Biophysics on Muck Rack

Single-molecule Biophysics

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Intramolecular photostabilization via triplet-state quenching: design principles to make organic fluorophores “self-healing”

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By Single-molecule Biophysics, Jaakko J. Uusitalo, Groningen Biomolecular Sciences, Lourens-Jan Ugen
| Chemistry World Verified
Covalent linkage of fluorophores and photostabilizers was recently revived as a strategy to make organic fluorophores “self-healing” via triplet-state quenching. Although Lüttke and co-workers pioneered this strategy already in the 1980s, the general design principles still remain elusive. In this contribution, we combine experiments and theory to understand what determines the photostabilization efficiency in dye–photostabilizer conjugates.
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