Somnath Arjun Borade

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Rhodium‐Catalyzed Regioselective C7Ar‐(Acyl)alkylation of Tryptophan With Allyl Alcohols and Its Late‐Stage Peptide Exemplification

Dec 02, 2025 |

By Mukul Yadav, Siva S. Panda, Disha Harsukhbhai Tank, Somnath Arjun Borade

| Wiley Online Library

An efficient Rh(III)-catalyzed pivaloyl-directed strategy has been developed for the C7Ar-(acyl)alkylation of tryptophans with substituted and unsubstituted allyl alcohols, delivering tryptophan-based unnatural amino acids without compromising their chirality.

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Somnath Arjun Borade

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Rhodium‐Catalyzed Regioselective C7Ar‐(Acyl)alkylation of Tryptophan With Allyl Alcohols and Its Late‐Stage Peptide Exemplification

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