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Anomalous vibrational properties and spin phase diagrams of $(\mathrm{Mg},\mathrm{Fe})\mathrm{C}{\mathrm{O}}_{3}$ under extreme conditions

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By Zhu Mao, Chaoshuai Zhao, Spivak Anna
| Physical Review B
(Mg,Fe)CO3 solid solutions not only play a crucial role in carbon storage and transport within the deep mantle, but also serve as a great case for studying the spin transition behavior of Fe2+ in the fairly isometric sixfold coordinated octahedral sites. However, simultaneously high temperature and pressure measurements on the spin crossover of (Mg,Fe)CO3 remain scarce, which greatly limits our knowledge about the pressure-induced spin transition of (Mg,Fe)CO3 under extreme conditions.
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