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Suparnak Midya on Muck Rack

Suparnak Midya

As seen in: Royal Society of Chemistry
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Articles

Ring-Expansion of Ketones with [1.1.1]Propellane

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By Ganesh Arjun Kadam, Suparnak Midya, Vitalina Levchenko, Vadym Sham
| dx.doi.org
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Highly diastereoselective strain-release Doyle-Kirmse reaction: access to functionalized difluoro(methylene)cyclopropanes

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By Suparnak Midya, Durga Prasad Hari
| Royal Society of Chemistry Verified
Highly diastereoselective strain-release Doyle-Kirmse reaction: access to functionalized difluoro(methylene)cyclopropanes Difluoro(methylene)cyclopropanes (F2MCPs) show better anti-cancer properties and chemical reactivities compared to their nonfluorinated analogues. However, catalytic stereoselective methods to access these privileged motifs still remain a challenging goal. The Doyle-Kirmse reaction is a powerful strategy for the concomitant formation of carbon-carbon and carbon-sulfur bonds.
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