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Solution and solid-state characterization of rare silyluranium(III) complexes
Solution and solid-state characterization of rare silyluranium(iii) complexes† A uranium(III) silylate complex [K(DME)4][UI2{(Si(SiMe3)2SiMe2)2O}] (1) was stabilized by the addition of 18-crown-6, forming [K(18-crown-6)][UI2{(Si(SiMe3)2SiMe2)2O}] (1-crown). Crystallization under multiple conditions resulted in three distinct molecular structures. Compound 1-crown was further characterized in the solution state via1H, 13C, and 29Si NMR spectroscopy, and electronic absorption spectroscopy.
Periodic Table Update: It is Time to Redecorate
In 2019, chemists around the world spent an entire year celebrating the Periodic Table. And what a year it was! There were special journal issues, spotlights in the popular media, and sessions at conferences dedicated to acknowledging and appreciating the main tool of our trade. The International Year of the Periodic Table (IYPT), as it was known, was all over social media and was spotlighted in many classrooms, seminars, and conferences around the world.
Ligand effects on electronic structure and bonding in U(III) coordination complexes: a combined MCD, EPR and computational study
Ligand effects on electronic structure and bonding in U(iii) coordination complexes: a combined MCD, EPR and computational study† Nikki J. Wolford, ‡a Xiaojuan Yu, ‡b Suzanne C. Bart, c Jochen Autschbach *b and Michael L.
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