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Thaddäus Thorwart

As seen in: Wiley Online Library, ACS Publications
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Articles

Aryl‐ and Silyl‐Substituted Silyliumylidene Ions in the Hydrosilylation of CO2

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By Sebastian Stigler, Thaddäus Thorwart, Lutz Greb, Shigeyoshi Inoue
| Wiley Online Library Verified
1 Introduction Low-valent group 14 compounds have emerged as a fast-evolving area of research in modern main-group chemistry.
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Structural Flexibility is a Decisive Factor in FLP Dihydrogen Cleavage with Tetrahedral Lewis Acids: A Silane Case Study

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By Thaddäus Thorwart, Lutz Greb
| Wiley Online Library Verified
Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.
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Redox‐Active Lewis Pairs Yield Diradicaloids and Enable Modular Control of the Diradical Character

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By Rezisha Maskey, Thaddäus Thorwart, Simone F. Ebel, Angelina Jocic
| Wiley Online Library Verified
Graphical Abstract Diradicaloid silicon oxolene salts are accessed through Lewis acid-base pairing of bis(catecholato)silanes with salts of dihydroxybenzoquinone. The features of the catecholates and the dihydroxybenzoquinone linker (electron donor or acceptor ability) control the diradical character of the adducts in a rational way. Abstract Stable metal-free diradicaloids are fascinating compounds, typically based on covalent polycyclic or nitrogen-containing π-conjugated frameworks.
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