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Amorphous intermediates and discovery of a kinetic polymorph of BiVO 4 from heating V+Bi+Zn single-source precursors
Abstract Molecular single-source precursors are a promising way of obtaining multi-element extended solids directly. We show that thermal decomposition of well-defined mono-, bi- and trimetallic polyoxovanadates (POVs) proceeds through a series of intermediate amorphous and crystalline species which we characterise using solid-state NMR spectroscopy, pair-distribution function (PDF) analysis and in-situ X-ray diffraction, before forming crystalline V2O5 and BiVO4 products.
Response to “Unexpected mutations after CRISPR–Cas9 editing <i>in vivo</i>”
The authors are employees of and stockholders in Intellia Therapeutics, Inc.
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