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Electron Spillover into Water Layers: A Quantum Leap in Understanding Capacitance Behavior

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By Lang Li, Karsten Reuter, Nicolas G. Hörmann, Thorben Eggert
| dx.doi.org
Introduction Click to copy section linkSection link copied! The structure and dielectric properties of the electric double layer (EDL) play a crucial role in determining the activity and selectivity of electrocatalytic reactions. (1−6) Experimental techniques such as impedance spectroscopy (7,8) and cyclic voltammetry (9−11) measure the capacitance of the EDL, thereby providing a macroscopic view of how adsorbates or surface modifications influence the electrode–electrolyte interface.
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