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Valentin M Aubert on Muck Rack

Valentin M Aubert

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Synthesis of Arylamines via Aminium Radicals

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By Thomas D. Svejstrup, Fabio Juliá, Daniele Leonori, Alessandro Ruffoni, Valentin M Aubert
| Color Research & Application Verified
Arylamines constitute the core structure of many therapeutic agents, agrochemicals and organic materials. The development of methodologies for the efficient and selective construction of these structural motifs from simple building blocks is desirable but still challenging. Here, we demonstrate that protonated electron poor O-aryl hydroxylamines lead, in the presence of Ru(bpy)3Cl2, to the formation of aminium radicals.
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