Vincent Chandra Hendrarta on Muck Rack

Vincent Chandra Hendrarta

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A Friedländer route to 5,7-Diazapentacenes

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By Sam Morris, Andrey V Lunchev, Vincent Chandra Hendrarta, Aparna Jaggi
| Royal Society of Chemistry
A route to compounds with a 5,7-diazapentacene skeleton has been established involving a Friedländer reaction. A diaminodiketone 8 has been made by a novel method and reacted with cyclohexanone to prepare an octa-hydro-5,7-diazapentacene 7a and with tetralone to produce a dibenzotetrahydro-5,7-diazapentacene 7b. Reaction of the diaminodiketone with a diarylethanone followed by oxidation gave a tetrabenzo-5,7-diazapentacene 18b.
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