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Vincent M. Groner

As seen in: ACS Publications
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Articles by Vincent M. Groner

Synthesis of Cp* Terphenylamido U(III) Iodide Complexes with a Substitutable Iodide Position to Generate Terminal U(III)-(κ3-BH4) Complexes

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By Vincent M. Groner, Iaroslav E. Gureev, Brennan S. Billow, Ivan Popov
| dx.doi.org
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Synthesis of Cp* Terphenylamido U(III) Iodide Complexes with a Substitutable Iodide Position to Generate Terminal U(III)-(κ3-BH4) Complexes

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By Brennan S. Billow, Ivan Popov, Vincent M. Groner, Iaroslav E. Gureev
| ACS Publications
Abstract Click to copy section linkSection link copied! Reaction of Cp*UI2(THF)3 (Cp* = pentamethylcyclopentadienide; THF = tetrahydrofuran) with NaR3TerNH (R3Ter = 2,6(2,4,6-R3C6H2)2C6H3; R = Me, Et, iPr) gave the U(III) monoiodide complexes Cp*(R3TerNH)UI (R = Me, 1-Me; R = Et, 2-Et; R = iPr, 3-iPr). These complexes contain a functionalizable iodide position which reacts favorably with NaBH4 to give the κ3-borohydride complexes Cp*(R3TerNH)U(H3BH) (R = Me, 4-Me; R = Et, 5-Et; R = iPr, 6-iPr).
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