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In recent years, functionalization of simple alkenes has developed into a powerful tool for generation of highly functionalized skeletons in organic synthesis [1,2]. In the past ten years, chemists have mainly focused on the addition of carbon- and heteroatom-centered radicals to π systems, including C C, C O, and C N double bonds, which serve as radical acceptors.
Introduction Malignant melanoma (MM) is the most lethal of all skin cancers. MM is a skin neoplasm resulting from the transformation and uncontrolled proliferation of melanocytes in the stratum basale of the skin [1]. Although it accounts for only 1% of all skin cancers, MM is a substantially deadly disease, accounting for 75% of all skin cancer deaths [2,3]. The global incidence of melanoma is rising faster than any other solid tumour in the last 50 years [4].
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