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W. Kice Brown on Muck Rack

W. Kice Brown

As seen in: Royal Society of Chemistry
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Unlocking metal coordination of diborylamides through ring constraints

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By W. Kice Brown, Kevin Klausmeyer, Brian M. Lindley
| Royal Society of Chemistry Verified
Unlocking metal coordination of diborylamides through ring constraints† A cyclic lithium diborylamide compound was synthesized and crystallographically characterized, revealing strong Li–N bonding in sharp contrast to previous linear diborylamides. Two iron(II) diborylamide complexes were also synthesized, including a 2-coordinate Fe bis(diborylamide) complex. The present cyclic diborylamide represents a new addition to the growing scope of amide ligands.
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