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Site-Specific Molecular Engineering Redirects Radical Pathways for Selective Photocatalytic Coupling of Methane to C 2+ Hydrocarbons
1 Introduction CH4, abundantly present in natural gas, shale gas, and combustible ice, is a key feedstock for fine chemical synthesis, yet its upgrading is thermodynamically challenging due to low polarity and high C─H bond dissociation energy [1-4]. Industrial routes like dry/steam reforming (>700°C) followed by Fischer–Tropsch synthesis are energy-intensive and carbon-emitting [5, 6].
Designing High-Performance Catalysts for Urea Electrosynthesis: Synergy between Single Atoms and BC₃ Monolayers
Designing High-Performance Catalysts for Urea Electrosynthesis: Synergy between Single Atoms and BC₃ Monolayers Electrochemical reduction of CO to value-added urea, achieved by coupling with N₂, offers a promising strategy for simultaneously addressing energy and environmental crises.
Peroxidase‐Mimetic Iron Silicate Nanosheets Coordinated with Indocyanine Green for Enhanced Anti‐Tumor Therapy
Conflict of Interest The authors declare no conflict of interest. Supporting Information Filename Description adhm202403002-sup-0001-SuppMat.docx37.2 MB Supporting Information References 1, , , , , , , , , , , , , , , , , , , , , , , , , , , , , , et al., Prog. Chem. 2023, 35, 1. 2, , , , Angew. Chem., Int. Ed. 2022, 61, e202200480. 3, , , , , , , , Adv. Mater. 2019, 31, 1902885. 4, , , , , , Chem.-Eur. J. 2022, 28, e202104081. 5, , Front. Bioeng. Biotech. 2022, 10, 880214. 6, , , , Front. Chem. 2022, 10, 1090795.
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