Xianglin Yin

Abstract Enhancing cycling reversibility in high-energy-density lithium metal batteries necessitates precise management of electrolyte-derived electrochemical reactions at electrodes and interphases, yet recently developed localized high-concentration electrolytes suffer from limited tunability of these reactions for the non-solvation-participating nature of oxygen-proximal fluorinated diluents.

Abstract The high flammability problem of Li metal negative electrode has persistently impeded the safe application of energy-dense Li metal batteries. Conventional flame-retardant mixing strategy also fails in addressing this challenge because of the severe function-destroying corrosion reaction between flame retardant and Li metal.

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